Browsing NCL Publications by Subject "carbonyls"

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Cosolvent Effects on Solute–Solvent Hydrogen-Bond Dynamics: Ultrafast 2D IR Investigations

Kashid, Somnath; Jin, Geun Young; Bagchi, Sayan; Kim, Yung Sam (The Journal of Physical Chemistry B, 2015-11-24)

Cosolvents strongly influence the solute–solvent interactions of biomolecules in aqueous environments and have profound effects on the stability and activity of several proteins and enzymes. Experimental studies have ...
Electrostatic Interactions Are Key to C═O n-π* Shifts: An Experimental Proof

Haldar, Tapas; Bagchi, Sayan (The Journal of Physical Chemistry Letters, 2016-06-01)

Carbonyl n-π* transitions are known to undergo blue shift in polar and hydrogen-bonding solvents. Using semiempirical expressions, previous studies hypothesized several factors like change in dipole moment and hydrogen-bond ...

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