dc.contributor.advisor |
Bagchi, Sayan |
|
dc.contributor.author |
Rai Deka, Jugal Kishore |
|
dc.contributor.author |
Sahariah, Biswajit |
|
dc.contributor.author |
Sakpal, Sushil |
|
dc.contributor.author |
Bar, Arun Kumar |
|
dc.contributor.author |
Bagchi, Sayan |
|
dc.contributor.author |
Sarma, Bani Kanta |
|
dc.date.accessioned |
2023-10-10T06:02:11Z |
|
dc.date.available |
2023-10-10T06:02:11Z |
|
dc.date.issued |
2021-05-11 |
|
dc.identifier.other |
https://doi.org/10.1021/acs.orglett.1c00834 |
|
dc.identifier.uri |
https://hdl.handle.net/20.500.12252/6249 |
|
dc.description.abstract |
1,2-Dibenzoyl-1-tert-butylhydrazine (RH-5849) and related N-alkyl-N,N′-diacylhydrazines are environmentally benign insect growth regulators. Herein, we show that an unusual nN(amide) → π*Ar interaction mediated by a hydrazide amide nitrogen atom plays a crucial role in stabilizing their biologically active trans–cis (t–c) rotameric conformations. We provide NMR and IR spectroscopic evidence for the presence of these interactions, which is also supported by X-ray crystallographic and computational studies. |
en |
dc.format.extent |
5 |
en |
dc.language.iso |
en_US |
en |
dc.publisher |
Organic Letters |
en |
dc.title |
Evidence of an nN(amide) → π*Ar Interaction in N-Alkyl-N,N′-diacylhydrazines |
en |
dc.type |
Article |
en |
local.division.division |
Physical and Materials Chemistry Division |
en |
dc.description.university |
-- |
en |